MilitaryCAC's U.S. Navy CAC Resource page
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Download and install the OS X Smartcard Services package The OS X Smartcard Services Package allows a Mac to read and communicate with a smart card. In order for your machine to recognize your CAC certificates and DoD websites as trusted, the installer will load the DoD CA certificates on OS X.
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Active Directory doesn't store network information for individual clients. Unless I'm missing something really obvious there isn't a MAC Address field for computer accounts in Active Directory. As you mention, you do have that information in DHCP, however, this is not published into AD and DHCP is held in a seperate database.
Install the SSO Client manually on each workstation. If you configure more than one Active Directory domain, your users must install the SSO Client. For more information, see Configure Active Directory Authentication. Deploy the SSO Client automatically to multiple workstations.